Browsing by Author "Ogunsemi, B. T."

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    Reinforcement bar corrosion - causes and management
    (IOP Publishing Ltd, 2019) Oki, M.; Akintola, S. A.; Adediran, A. A.; Peter, P.; Ikubanni, P. P.; Ogunsemi, B. T.
    Concretes are composite materials which decay as a result of steel corrosion in concrete structures is mostly accelerated in environments laden with chlorides and industrial effluent gases as well as harsh chemicals employed in and those generated from wastes in agricultural industries. This review summarises the effects of various environmental pollutants which promote deterioration of concretes with resultant corrosion of reinforcing bar (rebar). An overview of traditional and current methods for significant reduction of this mode of material deterioration is described. Discussions on management tools for rebar corrosion in agricultural and marine environments have been highlighted. Repair methods include the traditional application of patch repair mortar which has been modified with polymeric materials to improve adhesion and reduce porosity. The use of cathodic protection system to reduce rebar corrosion to its barest minimum has gained currency. Attention should be directed at corrosion reduction practices at the design and planning stages as well as modification concrete mixes with modified agricultural wastes/products and polymers.
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    Valorized chicken feather as corrosion inhibitor for mild steel in drilling mud
    (2019) Akintola, S. A.; Oki, M.; Aleem, A. A.; Adediran, A. A.; Akpor, O. B.; Oluba, O. M.; Ogunsemi, B. T.; Ikubanni, P. P.
    Modified chicken feather reduced the corrosion rate of mild steel in drilling mud as deduced from electrochemical potentiodynamic polarization technique, albeit, with observed infestation of the test environment by microbes over protracted exposure period of 92 days. The corrosion rates with and without the addition of 0.3g of hydrolyzed feather per 100 ml of drilling mud were 1.70 and 1.95 mm/yr, respectively; which corresponded to inhibition efficiency of 13% over the immersion period. The corresponding charge transfer resistances, a measure of corrosion rates were 1480.4 and 1780.0 Ω, respectively; in the uninhibited and hydrolyzed-feather inhibited environments. The voltage over the double layer capacitor as obtained from the polarization studies numerical increased from -0.907 to -0.948 V which indicated adsorption of moieties in the inhibitor and probably some corrosion products on the surface of the mild steel specimen.