FACULTY OF TECHNOLOGY
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Item Electron-optical and auger electron spectroscopy studies of a zirconium conversion coating on aluminium(2019) Adediran, A. A.; Oki, M.; Akintola, S. A.Item Electron-optical and auger electron spectroscopy studies of a zirconium conversion coating on aluminium(2019) Adediran, A. A.; Oki, M.; Akintola, S. A.Item Valorized chicken feather as corrosion inhibitor for mild steel in drilling mud(2019) Akintola, S. A.; Oki, M.; Aleem, A. A.; Adediran, A. A.; Akpor, O. B.; Oluba, O. M.; Ogunsemi, B. T.; Ikubanni, P. P.Modified chicken feather reduced the corrosion rate of mild steel in drilling mud as deduced from electrochemical potentiodynamic polarization technique, albeit, with observed infestation of the test environment by microbes over protracted exposure period of 92 days. The corrosion rates with and without the addition of 0.3g of hydrolyzed feather per 100 ml of drilling mud were 1.70 and 1.95 mm/yr, respectively; which corresponded to inhibition efficiency of 13% over the immersion period. The corresponding charge transfer resistances, a measure of corrosion rates were 1480.4 and 1780.0 Ω, respectively; in the uninhibited and hydrolyzed-feather inhibited environments. The voltage over the double layer capacitor as obtained from the polarization studies numerical increased from -0.907 to -0.948 V which indicated adsorption of moieties in the inhibitor and probably some corrosion products on the surface of the mild steel specimen.Item Conversion coating pretreatment enhances pipeline integrity(2018) Oki, M.; Adediran, A. A.; Ogunsemi, B.; Akintola, S. A.; Charles, E.It is necessary to coat both the internal and external surfaces of pipelines which transport different types of fluids that are usually contaminated with various percentages of aggressive corrosives. Pipelines pass through various terrains and highly challenging environments hence the need for both internal and external coatings to prevent corrosion and its adverse effects. In order to improve on the longevity of pipelines and the adhesion of the coating system, it is preferable to conversion coat blasted surfaces prior to application of any coating system. Improvements in pipeline coatings applications and the often neglected chromating procedure prior to coating application have been highlighted. This will prolong the lifespan of pipeline networks and secure these strategic assets from being a source of both materials and human resources drain pipes. However, the use of corrosion resistant alloys as internal lining for carbon steel pipes in the petroleum/gas industry is fast gaining recognition.Item Prediction of generalised and localised carbon steel corrosion using improved Norsok and Papavinasam models(2017) Falode, O. A.; Akintola, S. A.; Akintomiwa, I.In this study, Norsok and Papavinasam models have been improved so as to reduce the model limitations. The Norsok model was improved by accounting for 3 phase flow in calculating the wall shear stress and correcting for oil wetting and formation of protective layers in steel pipes during hydrocarbon transportation while the Papavinasam model was improved by using the Weibull distribution to account for time effect in corrosion predictions. The corrosion rates predicted fairly agreed with the field values. The improved models are user friendly and readily available and thus applicable for corrosion studies in the oil and gas industry.Item Comparative study of corrosion behaviour of nickel and gold plated carbon steels used as ornamentals in saline environment(Science and Academic Publishing, 2012) Oluwole, O. O.; Garus-Alaka, W.; Ajide, O. O.This study investigated the corrosion resistance of plated and unplated steels useful as ornamentals in saline environment. Nickel plating of carbon steel was done in watts solution for 25minutes with a current density of 3 Adm-3 at 60oC. The nickel plated carbon steel was later gold plated for 20 minutes with a current density of 0.2 Adm-3 at 50oC . The plated and unplated carbon steels were immersed in saline environment for 360 hours. Weight loss was taken every 24 hours in order to evaluate corrosion penetration rate (CPR). The results obtained showed that plated carbon steel generally offers a better corrosion resistance than the unplated one. Corrosion of ornamentals is equally gaining importance especially coated ornamentals. The use of nickel for ornamentals is gaining more prominence over silver rising due to its shiny surface and its cost. The use of nickel plated ornamentals just as gold plated ornamentals are being patronized will surely become common place due to affordability for the generality of people. However, the effects of everyday corrosive fluids from kitchen salt and low acidic media on the durability of the coatings need to be established. Carbon steel is the natural substrate used in ornamental coatings .The results also showed that a small thickness of gold plated carbon steel exhibited better corrosion resistance in saline environment. More also, gold plated carbon steel is found to be more suitable and reliable candidate material than nickel plated carbon steel in this environment although with higher costs.Item Comparative study of corrosion behaviour of nickel and gold plated carbon steels used as ornamentals in saline environment(Science and Academic Publishing, 2012) Oluwole, O. O.; Garus-Alaka, W.; Ajide, O. O.This study investigated the corrosion resistance of plated and unplated steels useful as ornamentals in saline environment. Nickel plating of carbon steel was done in watts solution for 25minutes with a current density of 3 Adm-3 at 60oC. The nickel plated carbon steel was later gold plated for 20 minutes with a current density of 0.2 Adm-3 at 50oC . The plated and unplated carbon steels were immersed in saline environment for 360 hours. Weight loss was taken every 24 hours in order to evaluate corrosion penetration rate (CPR). The results obtained showed that plated carbon steel generally offers a better corrosion resistance than the unplated one. Corrosion of ornamentals is equally gaining importance especially coated ornamentals. The use of nickel for ornamentals is gaining more prominence over silver rising due to its shiny surface and its cost. The use of nickel plated ornamentals just as gold plated ornamentals are being patronized will surely become common place due to affordability for the generality of people. However, the effects of everyday corrosive fluids from kitchen salt and low acidic media on the durability of the coatings need to be established. Carbon steel is the natural substrate used in ornamental coatings .The results also showed that a small thickness of gold plated carbon steel exhibited better corrosion resistance in saline environment. More also, gold plated carbon steel is found to be more suitable and reliable candidate material than nickel plated carbon steel in this environment although with higher costs.